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Adjust rack to middle position and preheat oven to 450 degrees. Wash and dry produce.
Peel and mince or grate garlic.
In a small, microwave-safe bowl, combine garlic with 2 TBSP butter (4 TBSP for 4 servings). Microwave until butter has melted, 30 seconds.
Brush pitas all over with garlic butter; cut each pita into 8 wedges. Arrange on a baking sheet; season generously all over with salt and pepper.
Bake on middle rack until chips are browned and crisp, 11-13 minutes. Wash out bowl.